It seems the consensus is to prioritize Sega Saturn over Sega CD since it seems there's already a decent source for those. I figure I'll pull a title from each end of the alphabet as I do these, which means, the massive bulk of sports games will be last (Madden, NBA, NFL, NHL, etc). I don't think there will be too many complaints there.
I should be able to get started next week. I'm coming off of a couple of weeks of 18 hour shifts to meet a project deadline at work, so I should have more time here in the mornings to do scans. Though, I have post-crunch vacation scheduled for August, so I'll be off the grid for a while then too.
As for hosting, I'm estimating that if I actually get through them all, it will be about 5GB of images. A 20 page manual came in right around 10MB (which means Sim City 2000 will run about 50MB

Anyone feel up for accepting/trading some DropBox email invites for manual scans?

Either that, or willing to give me a FTP to upload these to?